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                                       The Hodgson Group

 

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Publications:

    

         142)  'Aruncin B: Synthetic Studies, Structural Reassignment and Biological Evaluation'

A. Ribaucourt, C. Towers, L. Josa-Culleré, F. Willenbrock, A. L. Thompson, and D. M. Hodgson, Chem. Eur. J., 2017, 23Accepted Article

http://dx.doi.org/10.1002/chem.201702949. 

   


     

141) 'Synthesis of (−)-6,7-Dideoxysqualestatin H5 by Carbonyl Ylide Cycloaddition–Rearrangement and Cross-electrophile Coupling'

Y. Fegheh-Hassanpour, T. Arif, H. O. Sintim, H. H. Al Mamari and D. M. Hodgson, Org. Lett., 2017, 19, 3540. DOI: 10.1021/acs.orglett.7b01513

   

    

140) 'Total Synthesis and Structural Revision of the Cytotoxin Aruncin B'

A. Ribaucourt and D. M. Hodgson, Org. Lett., 2016, 18, 4364. DOI: 10.1021/acs.orglett.6b02120

   

 
       

139)  'α- and α'-Lithiation–Electrophile Trapping of N-Thiopivaloyl and N-t-Butoxythiocarbonyl α-Substituted Azetidines: Rationalization of the Regiodivergence Using NMR and Computation' K. E. Jackson, C. L. Mortimer, B. Odell, J. M. McKenna, T. D. W. Claridge, R. S. Paton and D. M. Hodgson, J. Org. Chem., 2015, 80, 9838 (Featured Article). DOI: 10.1021/acs.joc.5b01804

 


         

         138) 'Anomalous Nuclear Overhauser Effects in Carbon-Substituted Aziridines: Scalar Cross-Relaxation of the First Kind' I. Kuprov, D. M. Hodgson, J. Kloesges, C. I. Pearson, B. Odell and T. D. W. Claridge, Angew. Chem., Int. Ed., 2015, 54, 3697.

DOI: 10.1002/anie.201410271

                

             
137) 'Amine Protection/α-Activation with the tert-Butoxythiocarbonyl Group: Application to Azetidine Lithiation-Electrophilic Substitution' D. M. Hodgson, C. L. Mortimer and J. M. McKennaOrg. Lett., 2015, 17, 330. DOI: 10.1021/ol503441d

 

  

 

136) 'Intramolecular Oxonium Ylide Formation-[2,3] Sigmatropic Rearrangement of Diazocarbonyl-Substituted Cyclic Unsaturated Acetals: A Formal Synthesis of Hyperolactone C'  D. M. Hodgson, S. Man, K. J. Powell, Z. Perko, M. Zeng, E. Moreno-Clavijo, A. L. Thompson and M. D. Moore, J. Org. Chem., 2014, 79, 9728. DOI: 10.1021/jo501893r
 

 

135)  'Generation and Electrophile Trapping of N-Boc-2-Lithio-2-azetine: Synthesis of 2-Substituted-2-Azetines' D. M. Hodgson, C. I. Pearson and M. Kazmi, Org. Lett., 2014, 16, 856. DOI: 10.1021/ol403626k 

 

           

 

134) 'An Approach to Hyperolactone C and Analogues using Late Stage Conjugate Addition on an Oxonium Ylide-Derived Spirofuranone' D. M. Hodgson, E. Moreno-Clavijo, S. E. Day and S. Man, Org. Biomol. Chem., 2013, 11, 5362. DOI: 10.1039/C3OB41251B

 

 

133) 'C-Alkylation of Chiral Tropane- and Homotropane-Derived Enamines' D. M. Hodgson, A. Charlton, R. S. Paton and A. L. Thompson, J. Org. Chem. 2013, 78, 1508. DOI: 10.1021/jo3025972

 

 

132) 'α-Lithiation–Electrophile Trapping of N-Thiopivaloylazetidin-3-ol: Stereoselective Synthesis of 2-Substituted-3-hydroxyazetidines' D. M. Hodgson, C. I. Pearson and A. L. Thompson, J. Org. Chem. 2013, 78, 1098. DOI: 10.1021/jo3025225

 

 

131) 'Alkenes from β-lithiooxyphosphonium ylides generated by trapping α-lithiated terminal epoxides with triphenylphosphine' D. M. Hodgson and R. S. D. Persaud, Beilstein J. Org. Chem. 2012, 8, 1896. DOI: 10.3762/bjoc.8.219

 

 

130) 'Convergent Synthesis of Conjugated 1,2-Disubstituted E-Allylic Alcohols from Two Aldehydes and Methylenetriphenylphosphorane' D. M. Hodgson and R. S. D. Persaud, Org. Biomol. Chem., 2012, 10, 7949. DOI: 10.1039/C2OB26346G

 

 

129) 'syn-β-Hydroxyallylic Silanes from Terminal Epoxide α-Lithiation-Silylation and Alkenylation: Application to the Tetrahydrofuran Portion of the Lytophilippines'

D. M. Hodgson and S. Salik, Org. Lett., 2012, 14, 4402. DOI: 10.1021/ol3018853 

 

 

128) 'Synthesis of the Anti-trypanosomal Agent (±)- Hydroxyanthecotulide by Cr(II)-catalysed Allylation and Meyer-Schuster Rearrangement' D. M. Hodgson, E. P. A. Talbot and B. P. Clark, Chem. Commun., 2012, 48, 6349. Highlighted on the Chemical Communications blog. DOI: 10.1039/C2CC32283H

 

 

127) 'Unusual Base-Induced Rearrangement of exo-9-Oxabicyclo[4.2.1]non-7-ene Oxide to exo-8-Hydroxybicyclo[3.3.0]octan-2-one' D. M. Hodgson, M. A. H. Stent, R. S. Paton and F. X. Wilson, Heterocycles, 2012, 84, 625. (Prof. A Padwa 75th Birthday Issue). DOI: 10.3987/COM-11-S(P)35 

 

 

126) 'Catalytic Asymmetric Synthesis of (+)-Anthecotulide Using Enyne and Meyer–Schuster Rearrangements' D. M. Hodgson, E. P. A. Talbot, and B. P. Clark, Org. Lett. 2011, 13, 5751. DOI: 10.1021/ol202425e

 

 

125) 'Synthesis of the Anti-HIV Agent (-)-Hyperolactone C by using Oxonium Ylide Formation- Rearrangement' D. M. Hodgson and S. Man, Chem. Eur. J., 2011, 17, 9731. DOI: 10.1002/chem.201101082

 

 

 

124) 'Stereoselective Synthesis of β-(Hydroxymethylaryl/alkyl)-α-methylene-γ-butyrolactones' D. M. Hodgson, E. P. A. Talbot and B. P. Clark, Org. Lett., 2011, 13, 2594. DOI: 10.1021/ol200711f

 

 

123) 'Disubstituted Z-Allylic Esters by Wittig-Schlosser Reaction using Methylenetriphenylphosphorane' D. M. Hodgson and T. Arif, Chem. Commun., 2011, 47, 2685. DOI: 10.1039/C0CC04429F

 

 

122)   'α,β-Aziridinylphosphonates by Lithium Amide-Induced Phosphonyl Migration from N to C in Terminal Aziridines' D. M. Hodgson and X. Zu, Beilstein J. Org. Chem., 2010, 6, 978. DOI:10.3762/bjoc.6.110

 

 

 

121)   'Convergent Synthesis of Trisubstituted Z-Allylic Esters by Wittig-Schlosser Reaction' D. M. Hodgson and T. Arif, Org. Lett., 2010, 12, 4204. DOI: 10.1021/ol101843q  

 

 

120) 'Synthetic and Computational Studies on the Tricarboxylate Core of 6,7-Dideoxysqualestatin H5 Involving a Carbonyl Ylide Cycloaddition-Rearrangement' D. M. Hodgson, C. Villalonga-Barber, J. M. Goodman and S.C. Pellegrinet, Org. Biomol. Chem., 2010, 8, 3975. DOI: 10.1039/c004496b

 

 

119) 'Epoxide Opening-Induced Tandem 8-Azabicyclo[3.2.1]octane to 6-Azabicyclo[3.2.1]octane Rearrangement-Iminium Allylation: Synthesis of (±)-Peduncularine' D. M. Hodgson, R. E. Shelton, T. A. Moss and M. Dekhane, Org. Lett., 2010, 12, 2834. DOI: 10.1021/ol100943j

 

 

118) 'Transition States and Origins of 1,4-Asymmetric Induction in Alkylations of 2,2,6-Trialkylpiperidine Enamines' J. M. Um, N. S. Kaka, D. M. Hodgson and K. N. Houk, Chem. Eur. J., 2010, 16, 6310. DOI: 10.1002/chem.201000046

 

 

117) 'Lithiation−Electrophilic Substitution of N-Thiopivaloyl Azetidine' D. M. Hodgson and J. Kloesges, Angew. Chem., Int. Ed., 2010, 49, 2900. DOI: 10.1002/anie.201000058  

 

 

 

116) Stereocontrolled Syntheses of (–)-Cubebol and (–)-10-Epicubebol Involving Intramolecular Cyclopropanation of α-Lithiated Epoxides'  D. M. Hodgson, S. Salik and D. J. Fox, J. Org. Chem., 2010, 75, 2157. (incl. Cover Article).DOI: 10.1021/jo9022974

 

 

 

 

 

115) Radical Deoxygenation of 3-Azatricyclo[2.2.1.02,6]heptan-5-ols to 2-Azabicyclo[2.2.1]hept-5-enes and 1,2-Dihydropyridines' D. M. Hodgson, M. L. Jones, C. R. Maxwell, A. R. Cowley, A. L. Thompson, O. Ichihara and I. R. Matthews, Tetrahedron, 2009, 65,  7825. DOI:10.1016/j.tet.2009.07.022 

 

 

114) Synthesis of (-)-Cubebol by Intramolecular Cyclopropanation of a Terminal Epoxide' D. M. Hodgson and S. Salik, Synlett, 2009, 1730 (Thieme Chemistry Journal Awardee Article). DOI: 10.1055/s-0029-1217353

 

 

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113) Terminal Aziridines by Addition of Grignard Reagents or Organoceriums to an (α-Chloro)sulfinylimine' D. M. Hodgson, J. Kloesges and B. Evans, Synthesis, 2009, 1923 (Feature Article). DOI: 10.1055/s-0029-1216799

 

 

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112) Catalytic Enantioselective Tandem Carbonyl Ylide Formation - Intramolecular Cycloaddition with Unsaturated 2-Diazo-3,6-Diketo Sulfones' D. M. Hodgson, R. Glen and A. J. Redgrave, Tetrahedron: Asymmetry, 2009, 20, 754 (Prof. G. W. J. Fleet 65th Birthday Issue). DOI:10.1016/j.tetasy.2009.02.031

 

 

 

111) Synthesis and C-Alkylation of Hindered Aldehyde Enamines' D. M. Hodgson, C. D. Bray, N. D. Kindon, N. J. Reynolds, S. J. Coote, J. M. Um and K. N. Houk, J. Org. Chem., 2009, 74, 1019. DOI: 10.1021/jo802016t

 

 

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110) Consecutive Alkene Cross-Metathesis / Oxonium Ylide Formation-Rearrangement: Synthesis of the Anti-HIV Agent Hyperolactone C' D. M. Hodgson, D. Angrish, S. P. Erickson, J. Kloesges and C. H. Lee, Org. Lett., 2008, 10, 5533. DOI: 10.1021/ol802334y

 

 

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109) Convergent and Stereoselective Synthesis of Trisubstituted E-Alkenyl Bromides and Iodides via ß-Oxido Phosphonium Ylides' D. M. Hodgson and T. Arif, J. Am. Chem. Soc., 2008, 130, 16500. DOI: 10.1021/ja8076999

 

 

 

108) Asymmetric Synthesis of α-Alkylated Aldehydes using Terminal Epoxide-Derived Chiral Enamines' D. M. Hodgson and N. S. Kaka, Angew. Chem., Int. Ed., 2008, 47, 9958. DOI: 10.1002/ange.200804369

 

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107) Radical Cascades using Enantioenriched 7-Azabenzonorbornenes and their Applications in Synthesis' D. M. Hodgson and L. H. Winning, Beilstein J. Org. Chem., 2008, 4, No. 38. DOI:10.3762/bjoc.4.38

 

 

 

106) Terminal Aziridines by α-Deprotonation / Electrophile Trapping of N-Protected Aziridine' D. M. Hodgson, S. P. Hughes, A. L. Thompson and T. D. Heightman, Org. Lett., 2008, 10, 3453. DOI: 10.1021/ol801224g

 

 

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105) Asymmetric Synthesis of Terminal N-tert-Butylsulfinyl Aziridines from Organoceriums and an α-Chloroimine' D. M. Hodgson, J. Kloesges and B. Evans, Org. Lett., 2008, 10, 2781. DOI: 10.1021/ol800961a

 

 

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104) Dimerization and Isomerization Reactions of α-Lithiated Terminal Aziridines' D. M. Hodgson, P. G. Humphreys, S. M. Miles, C. A. J. Brierley and J. G. Ward, J. Org. Chem., 2007, 72, 10009. DOI: 10.1021/jo701901t

 

 

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103) Organolithiums and Lithium 2,2,6,6-Tetramethylpiperidide in Reductive Alkylation of Epoxides: Synthesis of (E)-Alkenes [(E)-2-Methyltetradeca-1,3-diene]' D. M. Hodgson, P. G. Humphreys and M. J. Fleming, Org. Synth., 2008, 85, 1. DOI

 

 

102) The Reactivity of Epoxides with Lithium 2,2,6,6-Tetramethylpiperidide in Combination with Organolithiums or Grignard Reagents' D. M. Hodgson, M. J. Fleming and S. J. Stanway, J. Org. Chem., 2007, 72, 4763. DOI: 10.1021/jo070291v

 

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101) Lithiation-Induced Migrations from Nitrogen to Carbon in Terminal Aziridines' D. M. Hodgson, P. G. Humphreys, Z. Xu and J. G. Ward, Angew. Chem., Int. Ed., 2007, 46, 2245. DOI: 10.1002/anie.200604920

 

 

 

 

100) Intramolecular Cyclopropanation of Unsaturated Terminal Epoxides and Chlorohydrins' D. M. Hodgson, Y. K. Chung, I. Nuzzo, G. Freixas, K. K. Kulikiewicz, E. Cleator and J.-M. Paris, J. Am. Chem. Soc., 2007, 129, 4456. DOI: 10.1021/ja0672932

 

 

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99) Highly Chemo- and Stereoselective Intermolecular Coupling of Diazoacetates to give cis-Olefins by using Grubbs Second-Generation Catalyst' D. M. Hodgson and D. Angrish, Chem. Eur. J., 2007, 13, 3470. DOI: 10.1002/chem.200601692

 

 

 

98) Organolithium-Induced Alkylative Ring Opening of Aziridines: Synthesis of Unsaturated Amino Alcohols and Ethers' D. M. Hodgson, B. Stefane, T. J. Miles and J. Witherington, J. Org. Chem., 2006, 71, 8510. DOI: 10.1021/jo0615201

 

 

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97) Oxapolycycles from One-pot Cross-Metathesis/Carbonyl Ylide Formation-Intramolecular Cycloaddition of α-Diazo-β-ketoesters' D. M. Hodgson and D. Angrish, Adv. Synth. Catal., 2006, 348, 2509 (Special Issue: Catalytic Cycloaddition Reactions).

DOI: 10.1002/adsc.200600306

 

 

96) Highly Enantioenriched 2-Azabenzonorbornenes from 7-Azabenzonorbornadienes by Asymmetric Hydroboration-Oxidation and Tandem Deoxygenation-Rearrangement-Electrophile Trapping' D. M. Hodgson and L. H. Winning, Synlett, 2006, 2476.

DOI: 10.1055/s-2006-950418

 

 

 

95) 3-Hydroxypyrrolidines from Epoxysulfonamides and Dimethylsulfoxonium Methylide' D. M. Hodgson, M. J. Fleming, Z. Xu, C. Lin and S. J. Stanway, Chem. Commun., 2006, 3226. DOI: 10.1039/b606583j

 

 

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94) Intramolecular Cyclopropanation of Unsaturated Terminal Aziridines' D. M. Hodgson, P. G. Humphreys and J. G. Ward, Org. Lett., 2006, 8, 995. DOI: 10.1021/ol060101n

 

 

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93) One-pot Cross-Metathesis/Tandem Carbonyl Ylide Formation - Intramolecular Cycloaddition of an Unsaturated 2-Diazo-3,6-diketoester' D. M. Hodgson, D. Angrish and A. H. Labande, Chem. Commun., 2006, 627. DOI: 10.1039/b515943a

 

 

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92) Unsymmetrical Maleates from Stereoselective Decomposition of Diazoesters using Grubbs' 2nd-Generation Ru Carbene Catalyst' D. M. Hodgson and D. Angrish, J. Mol. Catal. A: Chem., 2006, 254, 93 (Special Issue: The 16th. International Symposium on Olefin Metathesis and Related Chemistry). DOI:10.1016/j.molcata.2006.03.028

 

 

91) Dimerization of Lithiated Terminal Aziridines' D. M. Hodgson and S. M. Miles, Angew. Chem., Int. Ed., 2006, 45, 935. DOI: 10.1002/ange.200503303

 

 

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90) Stereocontrolled Synthesis of Kainoid Amino Acids from 7-Azabicyclo[2.2.1]heptadienes using Tandem Radical Addition-Homoallylic Radical Rearrangement' D. M. Hodgson, S. Hachisu and M. D. Andrews, J. Org. Chem., 2005, 70, 8866. DOI: 10.1021/jo0513865

 

 

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89) Maleates from Diazoacetates and Dilactones from Head-to-Head Dimerisation of Alkenyl Diazoacetates using Grubbs' 2nd-Generation Ruthenium Carbene Catalyst' D. M. Hodgson and D. Angrish, Chem. Commun., 2005, 4902 (incl. Cover Article; Hot Paper).

DOI: 10.1039/b510829b

 

 

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88) One-Carbon Homologation of N-Sulfonylaziridines to Allylic Amines using Dimethylsulfonium Methylide' D. M. Hodgson, M. J. Fleming and S. J. Stanway, Org. Lett., 2005, 7, 3295. DOI: 10.1021/ol051124p

 

 

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87) Intramolecular Cyclopropanation of Epichlorohydrin-Derived Unsaturated Chlorohydrins' D. M. Hodgson, Y. K. Chung and J.-M. Paris, Synthesis, 2005, 2264 (Practical Synthetic Procedure). DOI: 10.1055/s-2005-869973

 

 

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86) 2-Ene-1,4-diols by Dimerization of Terminal Epoxides using Hindered Lithium Amides' D. M. Hodgson, C. D. Bray and N. D. Kindon, Org. Lett., 2005, 7, 2305. DOI: 10.1021/ol050402h

 

 

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85) Enantioselective Access to Isoquinuclidines by Tropenone Desymmetrization and Homoallylic Radical Rearrangement: Synthesis of (+)-Ibogamine' D. M. Hodgson and J.-M. Galano, Org. Lett., 2005, 7, 2221. DOI: 10.1021/ol050627s

 

 

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84) Syntheses of (±)-a-Isokainic Acid and (±)-a-Dihydroallokainic Acid using a Decarboxylative Ramberg-Bäcklund Reaction' D. M. Hodgson, S. Hachisu and M. D. Andrews, Synlett, 2005, 1267. DOI: 10.1055/s-2005-868477

 

 

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83) 'Deprotonation - Electrophile Trapping of Terminal Epoxides' D. M. Hodgson, E. H. M. Kirton, S. M. Miles, S. L. M. Norsikian, N. J. Reynolds and S. J. Coote, Org. Biomol. Chem., 2005, 3, 1893 (Hot Paper). DOI: 10.1039/b502888d

 

 

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82) 'Substituted Aziridines by Lithiation-Electrophile Trapping of Terminal Aziridines' D. M. Hodgson, P. G. Humphreys and J. G. Ward, Org. Lett., 2005, 7, 1153. DOI: 10.1021/ol050060f

 

81) Synthesis of a-Kainic Acid from a 7-Azabicyclo[2.2.1]heptadiene by Tandem Radical Addition-Homoallylic Radical Rearrangement' D. M. Hodgson, S. Hachisu and M. D. Andrews, Org. Lett., 2005, 7, 815. DOI: 10.1021/ol047557u

 

 

 

 

80) Radical Deoxygenation of 3-Azatricyclo[2.2.1.02,6]heptan-5-ols to 1,2-Dihydropyridines' D. M. Hodgson, M. L. Jones, C. R. Maxwell, O. Ichihara and I. R. Matthews, Synlett, 2005, 325. DOI: 10.1055/s-2004-836066

 

79) Stereocontrolled Syntheses of the Nemorensic Acids using 6-Diazoheptane-2,5-dione in Carbonyl Ylide Cycloadditions' D. M. Hodgson, F. Le Strat, T. D. Avery, A. C. Donohue and T. Brückl, J. Org. Chem., 2004, 69, 8796. DOI: 10.1021/jo048446b

 

 

78) Substituted Epoxides by Lithiation of Terminal Epoxides' D. M. Hodgson, N. J. Reynolds and S. J. Coote, Org. Lett., 2004, 6, 4187. DOI: 10.1021/ol048544j

 

 

77) Alkenes from Terminal Epoxides Using Lithium 2,2,6,6-Tetramethylpiperidide and Organolithiums or Grignard Reagents' D. M. Hodgson, M. J. Fleming and S. J. Stanway, J. Am. Chem. Soc., 2004, 126, 12250. DOI: 10.1021/ja045513a

 

 

76) Unsaturated 1,2-Amino Alcohols and Ethers from Aziridines and Organolithiums' D. M. Hodgson, B. Stefane, T. J. Miles and J. Witherington, Chem. Commun., 2004, 2234.

DOI: 10.1039/b409486g

 

 

75) Intramolecular Cyclopropanation of Unsaturated Terminal Epoxides' D. M. Hodgson, Y. K. Chung and J.-M. Paris, J. Am. Chem. Soc., 2004, 126, 8664.

DOI: 10.1021/ja047346k

 

 

74) Epoxydisilanes by Direct Double Silylation of Terminal Epoxides ' D. M. Hodgson and E. H. M. Kirton, Synlett, 2004, 1610.

DOI: 10.1055/s-2004-829083

 

 

73) Studies on Organolithium-Induced Alkylative Desymmetrisation of Epoxides: Synthesis of Enantioenriched b-Amino Cycloheptenols from 6,7-Epoxy-8-azabicyclo[3.2.1]octanes' D. M. Hodgson and E. Paruch, Tetrahedron, 2004, 60, 5185.

DOI:10.1016/j.tet.2004.04.047 

 

 

72) Enamines from Terminal Epoxides and Hindered Lithium Amides' D. M. Hodgson, C. Bray and N. D. Kindon, J. Am. Chem. Soc., 2004, 126, 6870. DOI: 10.1021/ja031770o

 

 

71) Catalytic Enantioselective Intermolecular Cycloadditions of 2-Diazo-3,6-diketoester Derived Carbonyl Ylides with Alkene Dipolarophiles' D. M. Hodgson, T. Brückl, R. Glen, A. H. Labande, D. A. Selden, A. G. Dossetter and A. J. Redgrave, Proc. Natl. Acad. Sci. USA, 2004, 101, 5450. (Special Feature Issue: Asymmetric Catalysis). DOI:10.1073/pnas.0307274101

 

 

70) Organolithium-Induced Enantioselective Alkylative Double Ring-Opening of Epoxides: Synthesis of Enantioenriched Unsaturated Amino Alcohols' D. M. Hodgson, C. R. Maxwell, T. J. Miles, E. Paruch, I. R. Matthews and J. Witherington, Tetrahedron, 2004, 60, 3611.

DOI:10.1016/j.tet.2004.02.055 

 

 

69) Use of Allene in 1,3-Dipolar Addition to a Carbonyl Ylide: Syntheses of 3-Hydroxy-cis-nemorensic Acid and Nemorensic Acid' D. M. Hodgson and F. Le Strat, Chem. Commun., 2004, 821. DOI: 10.1039/b316908a

 

 

68) Enantioselective Synthesis of Epoxides by a-Deprotonation - Electrophile Trapping of Achiral Epoxides' D. M. Hodgson, T. J. Buxton, I. D. Cameron, E. Gras and E. H. M. Kirton, Org. Biomol. Chem., 2003, 1, 4293. DOI: 10.1039/B309717J

 

 

67) Synthesis and Evaluation of 4,4',6,6'-Tetrasubstituted Binaphtholphosphate Dirhodium(II) Complexes as Catalysts in Enantioselective Carbonyl Ylide Formation - Cycloaddition' D. M. Hodgson, D. A. Selden and A. G. Dossetter, Tetrahedron: Asymmetry, 2003, 14, 3841. DOI: 10.1016/j.tetasy.2003.09.029

 

 

66) Organolithium-Induced Synthesis of Acyclic Unsaturated Amino Alcohols from Epoxides of Dihydropyrroles and Tetrahydropyridines' D. M. Hodgson, T. J. Miles and J. Witherington, Tetrahedron, 2003, 59, 9729. (Symposium in-Print: Oxiranyl and Aziridinyl Anions as Reactive Intermediates in Synthetic Organic Chemistry). DOI: 10.1016/j.tet.2003.10.010

 

 

65) Synthesis of (-)-Xialenon A by Enantioselective a-Deprotonation-Rearrangement of a Meso-Epoxide' D. M. Hodgson, J.-M. Galano and M. Christlieb, Tetrahedron, 2003, 59, 9719. (Symposium in-Print: Oxiranyl and Aziridinyl Anions as Reactive Intermediates in Synthetic Organic Chemistry). DOI: 10.1016/j.tet.2003.09.023

 

 

64) Development of Two Processes for the Synthesis of Bridged Azabicyclic Systems: Intermolecular Radical Addition-Homoallylic Rearrangement to 2-Azanorborn-5-enes and Neophyl-Type Radical Rearrangements to 2-Azabenzonorbornanes' D. M. Hodgson, M. W. P. Bebbington and P. Willis, Org. Biomol. Chem., 2003, 1, 3787 (Dyson Perrins Laboratory Commemorative Issue). DOI: 10.1039/B306717N

 

 

63) The Scope of Catalytic Enantioselective Tandem Carbonyl Ylide Formation - Intramolecular [3+2] Cycloadditions' D. M. Hodgson, A. H. Labande, F. Y. T. M. Pierard and M. Á. Expósito Castro, J. Org. Chem., 2003, 68, 6153. DOI: 10.1021/jo0343735

 

 

62) Enantioselective Intramolecular 1,3-Dipolar Cycloadditions of Diazocarbonyl-Derived Oxidopyryliums'D. M. Hodgson, P. A. Stupple and C. Johnstone, Arkivoc, 2003 (vii), 49-58. (http://www.arkat-usa.org/ark/journal/2003/McKervey/AM-713D/713D.pdf) (Prof. M. A. McKervey Commemorative Issue).

 

 

61) Enantioselective Alkylative Double Ring-Opening of Epoxides Derived from Cyclic Allylic Ethers: Synthesis of Enantioenriched Unsaturated Diols' D. M. Hodgson, M. A. H. Stent, B. Stefane and F. X. Wilson, Org. Biomol. Chem., 2003, 1, 1139 (incl. Cover Article). DOI: 10.1039/B212404A

 

 

 

60) Catalytic Enantioselective Intermolecular Cycloadditions of a 2-Diazo-3,6-diketoester-Derived Carbonyl Ylide with Alkyne and Strained Alkene Dipolarophiles' D. M. Hodgson, A. H. Labande, R. Glen and A. J. Redgrave, Tetrahedron: Asymmetry, 2003, 14, 921 (Special Issue: Catalytic Asymmetric Carbene Transfer Reactions). DOI: 10.1016/S0957-4166(03)00036-3

 

 

59) Extended Scope of Dirhodium(II)-Catalysed Enantioselective Intramolecular 1,3-Dipolar Cycloadditions of Carbonyl Ylides with Alkene and Alkyne Dipolarophiles' D. M. Hodgson, A. H. Labande and F. Y. T. M. Pierard, Synlett, 2003, 59. DOI: 10.1055/s-2003-36218

 

 

58) Catalytic Enantioselective [3+2] Cycloadditions of Diazoketone-Derived Aryl-Substituted Carbonyl Ylides' D. M. Hodgson, R. Glen, G. H. Grant and A. J. Redgrave, J. Org. Chem., 2003, 68, 581. DOI: 10.1021/jo026307t

 

 

57) 2-Azabenzonorbornanes from 7-Azabenzonorbornanols by a Nitrogen-Directed Neophyl-Type Radical Rearrangement' D. M. Hodgson, M. W. P. Bebbington and P. Willis, Org. Lett., 2002, 4, 4353. DOI: 10.1021/ol027039o

 

 

56) Enantioselective Alkylative Double Ring-Opening of Epoxides: Synthesis of Enantioenriched Unsaturated Diols and Amino Alcohols' D. M. Hodgson, C. R. Maxwell, T. J. Miles, E. Paruch, M. A. H. Stent, I. R. Matthews, F. X. Wilson and J. Witherington, Angew. Chem., Int. Ed., 2002, 41, 4313. DOI: 10.1002/1521-3773(20021115)41:22<4313::AID-ANIE4313>3.0.CO;2-B

 

 

55) Enantioselective Total Synthesis of (-)-Xialenon A' D. M. Hodgson, J.-M. Galano and M. Christlieb, Chem. Commun., 2002, 2436. DOI: 10.1039/B208485F

 

 

54) Straightforward Synthesis of a,b-Epoxysilanes from Terminal Epoxides by Lithium 2,2,6,6-Tetramethylpiperidide-Mediated Deprotonation-in situ Silylation' D. M. Hodgson, N. J. Reynolds and S. J. Coote, Tetrahedron Lett., 2002, 43, 7895. DOI: 10.1016/S0040-4039(02)01893-2

 

 

53) Organolithium-Induced Synthesis of Unsaturated Diols from Epoxides of Dihydrofurans and Dihydropyrans' D. M. Hodgson, M. A. H. Stent and F. X. Wilson, Synthesis, 2002, 1445 (Feature Article). DOI: 10.1055/s-2002-33112

 

 

52) Chiral Epoxides by Desymmetrizing Deprotonation of Meso-Epoxides' D. M. Hodgson and E. Gras, Angew. Chem., Int. Ed., 2002, 41, 2376. DOI: 10.1002/1521-3773(20020703)41:13<2376::AID-ANIE2376>3.0.CO;2-Q

 

 

51) Concise, Stereoselective Syntheses of cis-Nemorensic Acid and 4-Hydroxy-cis-nemorensic Acid via Tandem Carbonyl Ylide Formation - Cycloaddition' D. M. Hodgson, T. D. Avery and A. C. Donohue, Org. Lett., 2002, 4, 1809. DOI: 10.1021/ol025917c

 

 

50) [3+2] Cycloaddition Reactions of Arylacetylenes with Carbonyl Ylides Derived from 1-Aryl-1-diazohexane-2,5-diones' D. M. Hodgson, R. Glen and A. J. Redgrave, Tetrahedron Lett., 2002, 43, 3927. DOI: 10.1016/S0040-4039(02)00630-5

 

 

49) Unsaturated 1,2-Amino Alcohols from Dihydropyrrole Epoxides and Organolithiums' D. M. Hodgson, T. J. Miles and J. Witherington, Synlett, 2002, 310. DOI: 10.1055/s-2002-19753

 

 

48) 6-Substituted 2-Azabicyclo[2.2.1]hept-5-enes by Nitrogen-Directed Radical Rearrangement: Synthesis of an Epibatidine Analogue with High Binding Affinity at the Nicotinic Acetylcholine Receptor' D. M. Hodgson, C. R. Maxwell, R. Wisedale, I. R. Matthews, K. J. Carpenter, A. H. Dickenson and S. Wonnacott, J. Chem. Soc., Perkin Trans. 1, 2001, 3150. DOI: 10.1039/B107414H

 

 

47) Substituted Alkenediols by Alkylative Double Ring-Opening of Dihydrofuran and Dihydropyran Epoxides' D. M. Hodgson, M. A. H. Stent and F. X. Wilson, Org. Lett., 2001, 3, 3401. DOI: 10.1021/ol016638c

 

 

46) Development of Dirhodium(II) Catalyzed Generation and Enantioselective 1,3-Dipolar Cycloaddition of Carbonyl Ylides' D. M. Hodgson, P. A. Stupple, F. Y. T. M. Pierard, A. H. Labande and C. Johnstone, Chem. Eur. J., 2001, 7, 4465 (incl. Cover Article). DOI: 10.1002/1521-3765(20011015)7:20<4465::AID-CHEM4465>3.0.CO;2-W

 

 

 

45) Functionalised Bicyclic Alcohols by Enantioselective a-Deprotonation-Rearrangement of Meso-Epoxides' D. M. Hodgson, I. D. Cameron, M. Christlieb, R. Green, G. P. Lee and L. A. Robinson, J. Chem. Soc., Perkin Trans. 1, 2001, 2161. DOI: 10.1039/B105369H

 

 

44) Rh(II) Binaphthol Phosphate Catalysts in Enantioselective Intramolecular Oxonium Ylide Formation - [3,2] Sigmatropic Rearrangement of a-Diazo-b-ketoesters' D. M. Hodgson and M. Petroliagi, Tetrahedron: Asymmetry, 2001, 12, 877. DOI: 10.1016/S0957-4166(01)00147-1

 

 

43) 2-Azabicyclo[2.2.1]hept-5-enes from 7-Azabicyclo[2.2.1]heptadienes by Tandem Intermolecular Radical Addition - Homoallylic Radical Rearrangement' D. M. Hodgson, M. W. P. Bebbington and P. Willis, Chem. Commun., 2001, 889. DOI: 10.1039/B101984H

 

 

42) First Direct Deprotonation-Electrophile Trapping of Simple Epoxides : Synthesis of a,b-Epoxysilanes from Terminal Epoxides' D. M. Hodgson and S. L. M. Norsikian, Org. Lett., 2001, 3, 461. DOI: 10.1021/ol006948f

 

 

41) Functionalized Bicyclo[3.3.0]octanes by Enantioselective Transannular Desymmetrization' D. M. Hodgson and I. D. Cameron, Org. Lett., 2001, 3, 441. DOI: 10.1021/ol006947n

 

 

40) Palladium-Catalysed Isomerisation of Vinyldisilanes to Allyldisilanes' D. M. Hodgson, S. F. Barker, L. H. Mace and J. R. Moran, Chem. Commun., 2001, 153. DOI: 10.1039/B008565K

 

 

39) Selectivity in the Cycloadditions of Carbonyl Ylides with Glyoxylates: an Approach to the Zaragozic Acids-Squalestatins' D. M. Hodgson, J. M. Bailey, C. Villalonga-Barber, M. G. B. Drew and T. Harrison, J. Chem. Soc., Perkin Trans. 1, 2000, 3432. DOI: 10.1039/B004870O

 

 

38) Studies Towards a Stereocontrolled Synthesis of the Tricarboxylate Core of the Zaragozic Acids-Squalestatins by a Cycloaddition-Rearrangement Strategy' D. M. Hodgson and C. Villalonga-Barber, Tetrahedron Lett., 2000, 41, 5597. DOI: 10.1016/S0040-4039(00)00873-X

 

 

37) Mechanism and Applications of Lithium Amide-Induced Asymmetric Rearrangements of 4-Substituted and 4,4-Disubstituted Cyclopentene Oxides to Cyclopentenols' D. M. Hodgson, A. R. Gibbs and M. G. B. Drew, J. Chem. Soc., Perkin Trans. 1, 1999, 3579. DOI: 10.1039/A907522D

 

 

36) On the Mechanism of Base-Induced Rearrangements of Epoxides to Ketones: a Formal Synthesis of (S)-Physoperuvine' D. M. Hodgson, L. A. Robinson and M. L. Jones, Tetrahedron Lett., 1999, 40, 8637. DOI: 10.1016/S0040-4039(99)01810-9

 

 

35) Efficient Rh(II) Binaphtholphosphate Catalysts for Enantioselective Intramolecular Tandem Carbonyl Ylide Formation-Cycloaddition of a-Diazo-b-ketoesters' D. M. Hodgson, P. A. Stupple and C. Johnstone, Chem. Commun., 1999, 2185. DOI: 10.1039/A906787F

 

 

34) A Stille Cyclisation Approach to (-)-Periplanone-B: Studies in Alkene-Selective Ring-Closing Metathesis and an Improved Chromium(II)-Mediated Synthesis of (E)-Alkenylstannanes from Aldehydes' D. M. Hodgson, A. M. Foley, L. T. Boulton, P. J. Lovell and G. N. Maw, J. Chem. Soc., Perkin Trans. 1, 1999, 2911. DOI: 10.1039/A905560F

 

 

33) On the Possibility of Carbamate-Directed Hydroboration. An Approach to the Asymmetric Synthesis of 1-Aminocyclopentane-1,3-dicarboxylic Acid' D. M. Hodgson, A. J. Thompson, S. Wadman and C. J. Keats, Tetrahedron, 1999, 55, 10815. DOI: 10.1016/S0040-4020(99)00596-7

 

 

32) Asymmetric Rearrangement of N-Boc 7-Azanorbornene Oxide: Use of Aryllithiums for Enantioselective Deprotonation' D. M. Hodgson, C. R. Maxwell and I. R. Matthews, Tetrahedron: Asymmetry, 1999, 10, 1847. DOI: 10.1016/S0957-4166(99)00168-8

 

 

31) Alkene Chemoselectivity in Ring-Closing Metathesis: a Formal Synthesis of (-)-Periplanone-B' D. M. Hodgson, A. M. Foley and P. J. Lovell, Synlett, 1999, 744. DOI: 10.1055/s-1999-2723

 

 

30) A New and Enantioselective Indolizidine Synthesis by meso-Epoxide a-Deprotonation - Transannular N-C Insertion' D. M. Hodgson and L. A. Robinson, Chem. Commun., 1999, 309. DOI: 10.1039/A809105F

 

 

29) An Epoxide Rearrangement - Radical Rearrangement Approach to 6-Substituted 2-Azabicyclo[2.2.1]-5-heptenes: Synthesis of an Epibatidine Analogue' D. M. Hodgson, C. R. Maxwell and I. R. Matthews, Synlett, 1998, 1349. DOI: 10.1055/s-1998-1963

 

 

28) Improved Cr(II)-Mediated Synthesis of E-Alkenylstannanes using Bu3SnCHI2 in DMF' D. M. Hodgson, A. M. Foley and P. J. Lovell, Tetrahedron Lett., 1998, 39, 6419. DOI: 10.1016/S0040-4039(98)01325-2

 

 

27) Isomerisations of Cycloalkene- and Bicycloalkene-Derived Achiral Epoxides by Enantioselective a-Deprotonation' D. M. Hodgson, G. P. Lee, R. E. Marriott, A. J. Thompson, R. Wisedale and J. Witherington, J. Chem. Soc., Perkin Trans. 1, 1998, 2151. DOI: 10.1039/A802434K

 

 

26) Carbamate-Directed Hydroboration: Enantioselective Synthesis of the Excitatory Amino Acid 1-Aminocyclopentane-1,3-dicarboxylic Acid' D. M. Hodgson, A. J. Thompson and S. Wadman, Tetrahedron Lett., 1998, 39, 3357. DOI: 10.1016/S0040-4039(98)00490-0

 

 

25) On the Mechanism of Lithium Amide-Induced Rearrangements of 4-Substituted Cyclopentene Oxides to Cyclopentenols' D. M. Hodgson and A. R. Gibbs, Tetrahedron Lett., 1997, 38, 8907. DOI: 10.1016/S0040-4039(97)10358-6

 

 

24) Catalytic Enantioselective Tandem Carbonyl Ylide Formation-Cycloaddition' D. M. Hodgson, P. A. Stupple and C. Johnstone, Tetrahedron Lett., 1997, 38, 6471. DOI: 10.1016/S0040-4039(97)01480-9

 

 

23) Chromium(II)-Mediated Synthesis of Vinyldisilanes from Aldehydes and a Study of Acid- and Base-Induced Reactions of the Derived Epoxydisilanes: a Synthesis of Acylsilanes' D. M. Hodgson, P. J. Comina and M. G. B. Drew, J. Chem. Soc., Perkin Trans. 1, 1997, 2279. DOI: 10.1039/A702722B

 

 

22) Ligand Effects in the Organolithium-Mediated Enantioselective a-Deprotonation of Achiral Epoxides' D. M. Hodgson and G. P. Lee, Tetrahedron: Asymmetry, 1997, 8, 2303. DOI: 10.1016/S0957-4166(97)00262-0

 

 

21) An Enantioselective Epoxide Rearrangement - Claisen Rearrangement Approach to Prostaglandins and (+)-Iridomyrmecin' D. M. Hodgson and A. R. Gibbs, Synlett, 1997, 657. DOI: 10.1055/s-1997-3253

 

 

20) Enantioselective Rearrangements of Bicyclo[2.2.1] and Bicyclo[2.2.2]alkene-Derived Achiral Epoxides to Ketones' D. M. Hodgson and R. E. Marriott, Tetrahedron: Asymmetry, 1997, 8, 519. DOI: 10.1016/S0957-4166(97)00014-1

 

 

19) Base-Induced Rearrangements of Bicyclo[2.2.1] and Bicyclo[2.2.2]alkene-Derived Epoxides to Ketones and Alcohols' D. M. Hodgson and R. E. Marriott, Tetrahedron Lett., 1997, 38, 887. DOI: 10.1016/S0040-4039(96)02432-X

 

 

18) A Remarkable Base-Induced Rearrangement of Epoxydisilanes' D. M. Hodgson and P. J. Comina, Tetrahedron Lett., 1996, 37, 5613-5614. DOI: 10.1016/0040-4039(96)01138-0

 

 

17) A Cycloaddition-Rearrangement Approach to the Squalestatins' D. M. Hodgson, J. M. Bailey and T. Harrison, Tetrahedron Lett., 1996, 37, 4623. DOI: 10.1016/0040-4039(96)00893-3

 

 

16) Enantioselective Rearrangement of exo-Norbornene Oxide to Nortricyclanol' D. M. Hodgson and R. Wisedale, Tetrahedron: Asymmetry, 1996, 7, 1275. DOI: 10.1016/0957-4166(96)00142-5

 

 

15) Enantioselective a-Deprotonation-Rearrangement of meso-Epoxides' D. M. Hodgson and G. P. Lee, Chem. Commun., 1996, 1015. DOI: 10.1039/CC9960001015

 

 

14) Vinyldisilanes as Masked Acylsilanes' D. M. Hodgson and P. J. Comina, Chem. Commun., 1996, 755. DOI: 10.1039/CC9960000755

 

 

13) Highly Enantioselective Rearrangement of Quaternary Carbon-Containing meso-Epoxides to Allylic Alcohols' D. M. Hodgson and A. R. Gibbs, Tetrahedron: Asymmetry, 1996, 7, 407. DOI: 10.1016/0957-4166(96)00019-5

 

 

12) An Efficient Medium-Ring Cyclisation Approach to the Germacranes' D. M. Hodgson, L. T. Boulton and G. N. Maw, Synlett, 1995, 267. DOI: 10.1055/s-1995-4933

 

 

11) Scope of the Chromium(II)-Mediated Synthesis of E-Alkenylstannanes from Aldehydes and Bu3SnCHBr2' D. M. Hodgson, L. T. Boulton and G. N. Maw, Tetrahedron, 1995, 51, 3713. DOI: 10.1016/0040-4020(95)00086-N

 

 

10) Pd/Cu Co-catalysed Cross-coupling Reactions of Methyl (Z)-2-Tributylstannyl-3-methoxypropenoate: a Method for Direct Introduction of the Agrochemically Important b-Methoxyacrylate Toxophore' D. M. Hodgson, J. Witherington, B. A. Moloney, I. C. Richards, and J.-L. Brayer, Synlett, 1995, 32. DOI: 10.1055/s-1995-4868

 

 

9) Chromium(II)-Mediated Synthesis of 1,1-Bis(trimethylsilyl)alkenes from Aldehydes and (Me3Si)2CBr2' D. M. Hodgson and P. J. Comina, Tetrahedron Lett., 1994, 35, 9469. DOI: 10.1016/S0040-4039(00)78573-X

 

 

8) Concise Racemic and Highly Enantioselective Approaches to Key Intermediates for the Syntheses of Carbocyclic Nucleosides and pseudo-Ribofuranoses: Formal Syntheses of Carbovir' D. M. Hodgson, J. Witherington and B. A. Moloney, J. Chem. Soc., Perkin Trans. 1, 1994, 3373. DOI: 10.1039/P19940003373

 

 

7) One-Step Chromium(II)-Mediated Homologation of Aldehydes to Methyl Ketones using Me3SiCBr3' D. M. Hodgson and P. J. Comina, Synlett, 1994, 663. DOI: 10.1055/s-1994-22967

 

 

6) Chemoselectivity in the Chromium(II)-Mediated Synthesis of E-Alkenylstannanes from Aldehydes and Bu3SnCHBr2' D. M. Hodgson, L. T. Boulton and G. N. Maw, Tetrahedron Lett., 1994, 35, 2231. DOI: 10.1016/S0040-4039(00)76805-5

 

 

5) Highly Enantioselective Rearrangement of a meso-Epoxide to an Allyl Alcohol for Carbocyclic Nucleoside Synthesis: an Internal Alkoxide Effect' D. M. Hodgson, J. Witherington and B. A. Moloney, Tetrahedron: Asymmetry, 1994, 5, 337. DOI: 10.1016/S0957-4166(00)86200-X

 

 

4) Chromium(II)-Mediated Nickel(II)-Catalysed Cyclisations of (Iodoaryl)-Substituted Alkynes and Alkynals' D. M. Hodgson and C. Wells, Tetrahedron Lett., 1994, 35, 1601. DOI: 10.1016/S0040-4039(00)76769-4

 

 

3) Regio- and Stereo-specific Synthesis of cis-(±)-1-Acetoxy-4-(acetoxymethyl)cyclopent-2-ene: a Key Intermediate in the Synthesis of Carbocyclic Nucleosides and pseudo-Ribofuranoses' D. M. Hodgson, J. Witherington and B. A. Moloney, J. Chem. Soc., Perkin Trans. 1, (Perkin Communication), 1993, 1543. DOI: 10.1039/P19930001543

 

 

2) Chromium(II)-Mediated Synthesis of E-Alkenylstannanes from Aldehydes and Bu3SnCHBr2' D. M. Hodgson, Tetrahedron Lett., 1992, 33, 5603. DOI: 10.1016/S0040-4039(00)61158-9

 

 

1) Regio- and Stereo-Selective Reactions of Trimethylsilyl-Substituted Allyl-Chromium Reagents with Aldehydes' D. M. Hodgson and C. Wells, Tetrahedron Lett., 1992, 33, 4761. DOI: 10.1016/S0040-4039(00)61279-0